Chemistry: Structure and Properties, Global Edition
Höfundur:
Nivaldo J. Tro (Útgáfa: 3)
Kaup valmöguleikar
For courses in 2-semester general chemistry. A focused atoms-first approach to learning chemistry With Chemistry: Structure and Properties, author Nivaldo Tro tells the story of chemistry with an atoms-first approach, emphasizing that matter is composed of particles and the structure of those particles determines the properties of matter. This relationship is the thread that weaves all of chemistry together and is applied to all aspects of the text.
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- Pearson International Content
- 9781292767192
- 9781292767178
- ePub
- 3
- Nivaldo J. Tro
- English
- 2026-05-27
- 100
- 2
- 2
Kaflar
- Cover
- Cover
- Front Matter
- Title page
- Copyright
- About the Author
- Brief Contents
- Preface
- Acknowledgments
- Global Edition Acknowledgments
- What’s New in This Edition
- Contents
- Contents
- E: Essentials: Units, Measurement, and Problem Solving
- Introduction: Essentials: Units, Measurement, and Problem Solving
- E.1: The Metric Mix-up: A $125 Million Unit Error
- E.2: The Units of Measurement
- E.3: The Reliability of a Measurement
- E.4: Significant Figures in Calculations
- E.5: Density
- E.6: Energy and Its Units
- E.7: Converting between Units
- E.8: Problem-Solving Strategies
- E.9: Solving Problems Involving Equations
- Chapter Summary: Essentials: Units, Measurement, and Problem Solving
- Exercises: Essentials: Units, Measurement, and Problem Solving
- 1: Atoms
- Introduction: Atoms
- 1.1: A Particulate View of the World: Structure Determines Properties
- 1.2: Classifying Matter: A Particulate View
- 1.3: The Scientific Approach to Knowledge
- 1.4: Early Ideas about the Building Blocks of Matter
- 1.5: Modern Atomic Theory and the Laws That Led to It
- 1.6: The Discovery of the Electron
- 1.7: The Structure of the Atom
- 1.8: Subatomic Particles: Protons, Neutrons, and Electrons
- 1.9: Atomic Mass: The Average Mass of an Element’s Atoms
- 1.10: Atoms and the Mole: How Many Particles?
- 1.11: The Origins of Atoms and Elements
- Chapter Summary: Atoms
- Exercises: Atoms
- 2: The Quantum-Mechanical Model of the Atom
- Introduction: The Quantum-Mechanical Model of the Atom
- 2.1: Schrödinger’s Cat
- 2.2: The Nature of Light
- 2.3: Atomic Spectroscopy and the Bohr Model
- 2.4: The Wave Nature of Matter: The de Broglie Wavelength, the Uncertainty Principle, and Indeterminacy
- 2.5: Quantum Mechanics and the Atom
- 2.6: The Shapes of Atomic Orbitals
- Chapter Summary: The Quantum-Mechanical Model of the Atom
- Exercises: The Quantum-Mechanical Model of the Atom
- 3: Periodic Properties of the Elements
- Introduction: Periodic Properties of the Elements
- 3.1: Aluminum: Low-Density Atoms Result in Low-Density Metal
- 3.2: The Periodic Law and the Periodic Table
- 3.3: Electron Configurations: How Electrons Occupy Orbitals
- 3.4: Electron Configurations, Valence Electrons, and the Periodic Table
- 3.5: Electron Configurations and Elemental Properties
- 3.6: Periodic Trends in Atomic Size and Effective Nuclear Charge
- 3.7: Ions: Electron Configurations, Magnetic Properties, Radii, and Ionization Energy
- 3.8: Electron Affinities and Metallic Character
- 3.9: Periodic Trends Summary
- Chapter Summary: Periodic Properties of the Elements
- Exercises: Periodic Properties of the Elements
- 4: Molecules and Compounds
- Introduction: Molecules and Compounds
- 4.1: Hydrogen, Oxygen, and Water
- 4.2: Types of Chemical Bonds
- 4.3: Representing Compounds: Chemical Formulas and Molecular Models
- 4.4: The Lewis Model: Representing Valence Electrons with Dots
- 4.5: Ionic Bonding: The Lewis Model and Lattice Energies
- 4.6: Ionic Compounds: Formulas and Names
- 4.7: Covalent Bonding: Simple Lewis Structures
- 4.8: Molecular Compounds: Formulas and Names
- 4.9: Formula Mass and the Mole Concept for Compounds
- 4.10: Composition of Compounds
- 4.11: Determining a Chemical Formula from Experimental Data
- 4.12: Organic Compounds
- Chapter Summary: Molecules and Compounds
- Exercises: Molecules and Compounds
- 5: Chemical Bonding I: Drawing Lewis Structures and Determining Molecular Shapes
- Introduction: Chemical Bonding I: Drawing Lewis Structures and Determining Molecular Shapes
- 5.1: Morphine: A Molecular Impostor
- 5.2: Electronegativity and Bond Polarity
- 5.3: Writing Lewis Structures for Molecular Compounds and Polyatomic Ions
- 5.4: Resonance and Formal Charge
- 5.5: Exceptions to the Octet Rule: Odd-Electron Species, Incomplete Octets, and Expanded Octets
- 5.6: Bond Energies and Bond Lengths
- 5.7: VSEPR Theory: The Five Basic Shapes
- 5.8: VSEPR Theory: The Effect of Lone Pairs
- 5.9: VSEPR Theory: Predicting Molecular Geometries
- 5.10: Molecular Shape and Polarity
- Chapter Summary: Chemical Bonding I: Drawing Lewis Structures and Determining Molecular Shapes
- Exercises: Chemical Bonding I: Drawing Lewis Structures and Determining Molecular Shapes
- 6: Chemical Bonding II: Valence Bond Theory and Molecular Orbital Theory
- Introduction: Chemical Bonding II: Valence Bond Theory and Molecular Orbital Theory
- 6.1: Oxygen: A Magnetic Liquid
- 6.2: Valence Bond Theory: Orbital Overlap as a Chemical Bond
- 6.3: Valence Bond Theory: Hybridization of Atomic Orbitals
- 6.4: Molecular Orbital Theory: Electron Delocalization
- 6.5: Molecular Orbital Theory: Polyatomic Molecules
- Chapter Summary: Chemical Bonding II: Valence Bond Theory and Molecular Orbital Theory
- Exercises: Chemical Bonding II: Valence Bond Theory and Molecular Orbital Theory
- 7: Chemical Reactions and Chemical Quantities
- Introduction: Chemical Reactions and Chemical Quantities
- 7.1: Climate Change and the Combustion of Fossil Fuels
- 7.2: Chemical and Physical Change
- 7.3: Writing and Balancing Chemical Equations
- 7.4: Reaction Stoichiometry: How Much Carbon Dioxide?
- 7.5: Stoichiometric Relationships: Limiting Reactant, Theoretical Yield, Percent Yield, and Reactant in Excess
- 7.6: Three Examples of Chemical Reactions: Combustion, Alkali Metals, and Halogens
- Chapter Summary: Chemical Reactions and Chemical Quantities
- Exercises: Chemical Reactions and Chemical Quantities
- 8: Introduction to Solutions and Aqueous Reactions
- Introduction: Introduction to Solutions and Aqueous Reactions
- 8.1: Molecular Gastronomy
- 8.2: Solution Concentration
- 8.3: Solution Stoichiometry
- 8.4: Types of Aqueous Solutions and Solubility
- 8.5: Precipitation Reactions
- 8.6: Representing Aqueous Reactions: Molecular, Ionic, and Complete Ionic Equations
- 8.7: Acid–Base Reactions
- 8.8: Gas-Evolution Reactions
- 8.9: Oxidation–Reduction Reactions
- Chapter Summary: Introduction to Solutions and Aqueous Reactions
- Exercises: Introduction to Solutions and Aqueous Reactions
- 9: Thermochemistry
- Introduction: Thermochemistry
- 9.1: Fire and Ice
- 9.2: The Nature of Energy: Key Definitions
- 9.3: The First Law of Thermodynamics: Nothing Is Free
- 9.4: Quantifying Heat and Work
- 9.5: Measuring ΔE for Chemical Reactions: Constant-Volume Calorimetry
- 9.6: Enthalpy: The Heat Evolved in a Chemical Reaction at Constant Pressure
- 9.7: Measuring ΔH for Chemical Reactions: Constant-Pressure Calorimetry
- 9.8: Relationships Involving ΔHrxn
- 9.9: Determining Enthalpies of Reaction from Bond Energies
- 9.10: Determining Enthalpies of Reaction from Standard Enthalpies of Formation
- 9.11: Lattice Energies for Ionic Compounds
- Chapter in Review: Thermochemistry
- Exercises: Thermochemistry
- 10: Gases
- Introduction: Gases
- 10.1: Supersonic Skydiving and the Risk of Decompression
- 10.2: A Particulate Model for Gases: Kinetic Molecular Theory
- 10.3: Pressure: The Result of Particle Collisions
- 10.4: The Simple Gas Laws: Boyle’s Law, Charles’s Law, and Avogadro’s Law
- 10.5: The Ideal Gas Law
- 10.6: Applications of the Ideal Gas Law: Molar Volume, Density, and Molar Mass of a Gas
- 10.7: Mixtures of Gases and Partial Pressures
- 10.8: Temperature and Molecular Velocities
- 10.9: Mean Free Path, Diffusion, and Effusion of Gases
- 10.10: Gases in Chemical Reactions: Stoichiometry Revisited
- 10.11: Real Gases: The Effects of Size and Intermolecular Forces
- Chapter Summary: Gases
- Exercises: Gases
- 11: Liquids, Solids, and Intermolecular Forces
- Introduction: Liquids, Solids, and Intermolecular Forces
- 11.1: Water, No Gravity
- 11.2: Solids, Liquids, and Gases: A Molecular Comparison
- 11.3: Intermolecular Forces: The Forces That Hold Condensed States Together
- 11.4: Intermolecular Forces in Action: Surface Tension, Viscosity, and Capillary Action
- 11.5: Vaporization and Vapor Pressure
- 11.6: Sublimation and Fusion
- 11.7: Heating Curve for Water
- 11.8: Phase Diagrams
- 11.9: Water: An Extraordinary Substance
- Chapter Summary: Liquids, Solids, and Intermolecular Forces
- Exercises: Liquids, Solids, and Intermolecular Forces
- 12: Crystalline Solids and Modern Materials
- Introduction: Crystalline Solids and Modern Materials
- 12.1: Friday Night Experiments: The Discovery of Graphene
- 12.2: Crystalline Solids: Determining Their Structures by X-Ray Crystallography
- 12.3: Crystalline Solids: Unit Cells and Basic Structures
- 12.4: Crystalline Solids: The Fundamental Types
- 12.5: The Structures of Ionic Solids
- 12.6: Network Covalent Atomic Solids: Carbon and Silicates
- 12.7: Ceramics, Cement, and Glass
- 12.8: Semiconductors and Band Theory
- 12.9: Polymers and Plastics
- Chapter Summary: Crystalline Solids and Modern Materials
- Exercises: Crystalline Solids and Modern Materials
- 13: Solutions
- Introduction: Solutions
- 13.1: Antifreeze in Frogs
- 13.2: Types of Solutions and Solubility
- 13.3: Energetics of Solution Formation
- 13.4: Solution Equilibrium and Factors Affecting Solubility
- 13.5: Expressing Solution Concentration
- 13.6: Colligative Properties: Vapor Pressure Lowering, Freezing Point Depression, Boiling Point Elevation, and Osmotic Pressure
- 13.7: Colligative Properties of Strong Electrolyte Solutions
- Chapter Summary: Solutions
- Exercises: Solutions
- 14: Chemical Kinetics
- Introduction: Chemical Kinetics
- 14.1: Catching Lizards
- 14.2: Rates of Reaction and the Particulate Nature of Matter
- 14.3: Defining and Measuring the Rate of a Chemical Reaction
- 14.4: The Rate Law: The Effect of Concentration on Reaction Rate
- 14.5: The Integrated Rate Law: The Dependence of Concentration on Time
- 14.6: The Effect of Temperature on Reaction Rate
- 14.7: Reaction Mechanisms
- 14.8: Catalysis
- Chapter Summary: Chemical Kinetics
- Exercises: Chemical Kinetics
- 15: Chemical Equilibrium
- Introduction: Chemical Equilibrium
- 15.1: Fetal Hemoglobin and Equilibrium
- 15.2: The Concept of Dynamic Equilibrium
- 15.3: The Equilibrium Constant (K)
- 15.4: Expressing the Equilibrium Constant in Terms of Pressure
- 15.5: Heterogeneous Equilibria: Reactions Involving Solids and Liquids
- 15.6: Calculating the Equilibrium Constant from Measured Equilibrium Concentrations
- 15.7: The Reaction Quotient: Predicting the Direction of Change
- 15.8: Finding Equilibrium Concentrations
- 15.9: Le Châtelier’s Principle: How a System at Equilibrium Responds to Disturbances
- Chapter Summary: Chemical Equilibrium
- Exercises: Chemical Equilibrium
- 16: Acids and Bases
- Introduction: Acids and Bases
- 16.1: Batman’s Basic Blunder
- 16.2: The Nature of Acids and Bases
- 16.3: Definitions of Acids and Bases
- 16.4: Acid Strength and Molecular Structure
- 16.5: Acid Strength and the Acid Ionization Constant (Ka)
- 16.6: Autoionization of Water and pH
- 16.7: Finding the [H3O+] and pH of Strong and Weak Acid Solutions
- 16.8: Finding the [OH−] and pH of Strong and Weak Base Solutions
- 16.9: The Acid–Base Properties of Ions and Salts
- 16.10: Polyprotic Acids
- 16.11: Lewis Acids and Bases
- Chapter Summary: Acids and Bases
- Exercises: Acids and Bases
- 17: Aqueous Ionic Equilibrium
- Introduction: Aqueous Ionic Equilibrium
- 17.1: The Danger of Antifreeze
- 17.2: Buffers: Solutions That Resist pH Change
- 17.3: Buffer Effectiveness: Buffer Range and Buffer Capacity
- 17.4: Titrations and pH Curves
- 17.5: Solubility Equilibria and the Solubility Product Constant
- 17.6: Precipitation
- 17.7: Complex Ion Equilibria
- Chapter Summary: Aqueous Ionic Equilibrium
- Exercises: Aqueous Ionic Equilibrium
- 18: Free Energy and Thermodynamics
- Introduction: Free Energy and Thermodynamics
- 18.1: Nature’s Heat Tax: You Can’t Win and You Can’t Break Even
- 18.2: Spontaneous and Nonspontaneous Processes
- 18.3: Entropy and the Second Law of Thermodynamics
- 18.4: Entropy Changes Associated with State Changes
- 18.5: Heat Transfer and Entropy Changes of the Surroundings
- 18.6: Gibbs Free Energy
- 18.7: Entropy Changes in Chemical Reactions: Calculating ΔSrxn°
- 18.8: Free Energy Changes in Chemical Reactions: Calculating ΔGrxn°
- 18.9: Free Energy Changes for Nonstandard States: The Relationship between ΔGrxn° and ΔGrxn
- 18.10: Free Energy and Equilibrium: Relating ΔGrxn° to the Equilibrium Constant (K)
- Chapter Summary: Free Energy and Thermodynamics
- Exercises: Free Energy and Thermodynamics
- 19: Electrochemistry
- Introduction: Electrochemistry
- 19.1: Lightning and Batteries
- 19.2: Balancing Oxidation–Reduction Equations
- 19.3: Voltaic (or Galvanic) Cells: Generating Electricity from Spontaneous Chemical Reactions
- 19.4: Standard Electrode Potentials
- 19.5: Cell Potential, Free Energy, and the Equilibrium Constant
- 19.6: Cell Potential and Concentration
- 19.7: Batteries: Using Chemistry to Generate Electricity
- 19.8: Electrolysis: Driving Nonspontaneous Chemical Reactions with Electricity
- 19.9: Corrosion: Undesirable Redox Reactions
- Chapter Summary: Electrochemistry
- Exercises: Electrochemistry
- 20: Radioactivity and Nuclear Chemistry
- Introduction: Radioactivity and Nuclear Chemistry
- 20.1: Diagnosing Appendicitis
- 20.2: The Discovery of Radioactivity
- 20.3: Types of Radioactivity
- 20.4: The Valley of Stability: Predicting the Type of Radioactivity
- 20.5: Detecting Radioactivity
- 20.6: The Kinetics of Radioactive Decay and Radiometric Dating
- 20.7: The Discovery of Fission: The Atomic Bomb and Nuclear Power
- 20.8: Converting Mass to Energy: Mass Defect and Nuclear Binding Energy
- 20.9: Nuclear Fusion: The Power of the Sun
- 20.10: Nuclear Transmutation and Transuranium Elements
- 20.11: The Effects of Radiation on Life
- 20.12: Radioactivity in Medicine and Other Applications
- Chapter Summary: Radioactivity and Nuclear Chemistry
- Exercises: Radioactivity and Nuclear Chemistry
- 21: Organic Chemistry
- Introduction: Organic Chemistry
- 21.1: Fragrances and Odors
- 21.2: Carbon: Why It Is Unique
- 21.3: Hydrocarbons: Compounds Containing Only Carbon and Hydrogen
- 21.4: Alkanes: Saturated Hydrocarbons
- 21.5: Alkenes and Alkynes
- 21.6: Hydrocarbon Reactions
- 21.7: Aromatic Hydrocarbons
- 21.8: Functional Groups
- 21.9: Alcohols
- 21.10: Aldehydes and Ketones
- 21.11: Carboxylic Acids and Esters
- 21.12: Ethers
- 21.13: Amines
- Chapter Summary: Organic Chemistry
- Exercises: Organic Chemistry
- 22: Transition Metals and Coordination Compounds
- Introduction: Organic Chemistry
- 22.1: The Colors of Rubies and Emeralds
- 22.2: Properties of Transition Metals
- 22.3: Coordination Compounds
- 22.4: Structure and Isomerization
- 22.5: Bonding in Coordination Compounds
- 22.6: Applications of Coordination Compounds
- Chapter Summary: Transition Metals and Coordination Compounds
- Exercises: Transition Metals and Coordination Compounds
- Backmatter
- Appendix I: Common Mathematical Operations in Chemistry
- Appendix II: Useful Data
- Appendix III: Answers to Selected End-of-Chapter Problems
- Appendix IV: Answers to In-Chapter Practice Problems
- List of Elements with Their Symbols and Atomic Masses
- Periodic Table
- Conversion Factors and Relationships
- Selected Key Equations
- Math and Chemistry-Based Glossary
- Credits
- Glossary